In Gotham City, an award show is being held where Gotham's finest is attending. The "Man of the Year" award is being presented to Bruce Wayne with Lex Luthor being runner-up. All is well until a group of Batman's villains (consisting of Penguin, Riddler, Harley Quinn, Two-Face, and Joker) show up as Joker steals the award thinking that he is more deserving of the title. Bruce Wayne steps out and changes into the Batsuit and becomes Batman. Along with Robin, Batman confronts and defeats all of the villains, but Joker escapes. After an extended chase, Batman captures Joker and he is thrown into Arkham Asylum. Sometime later, Lex Luthor arrives at the asylum and breaks the Joker out using a weapon called "The Deconstructor" (which deconstructs unbreakable black objects, and is powered only by kryptonite). Joker then uses the weapon to release all of the inmates from Arkham Asylum. Batman is called in to round up the villains. After capturing several of the villains in Arkham Asylum's maze, he discovers pieces of bricks that have the energy signature from Lex Luthor's weapon. After learning of a break-in at Ace Chemicals, Batman and Robin search for clues as to what the Joker is up to. After an explosion begins to destroy the factory, the Dynamic Duo are rescued by Superman. Batman then learns what the Joker was up to. The chemicals stolen from the plant that although not particularly dangerous alone can be combined to form a synthetic Kryptonite. Punching the signature into the Batmobile's on-board computer, Batman and Robin catch up to Lex Luthor's convoy and infiltrate it. After a brief skirmish, Batman is thrown out of the massive convoy and enters the Batmobile. Unfortunately, Joker has completed his synthetic Kryptonite (which is used to power Luthor's weapon) and uses it to blast apart the Batmobile. Back at the Batcave, Batman is trying to figure out Luthor's next move. He determines the new Kryptonite is harmless, but it proves to be a tracking device which leads Luthor and Joker to the cave. Batman has a Kryptonite Vault, which he uses 'In case Superman turns evil', which The Joker knew about. Using the Deconstructor, the villains destroy the cave, escaping with a load of Kryptonite. Having no way out, Batman reluctantly allows Robin to call Superman for help and they escape the collapsing cave...
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